4K UHD used to work fine on Prime Video when side loaded on Mi Box. It stopped working about an year back. Now, with 4.13.3-googleplay-armv7a, 4K UHD is back. Even HDR works!
Now, when you login for the first time on this app, it recognises the Mi Box as Xioami set top box. Earlier it used to recognsie the device as nVidia Shield.
Looks like Prime Video will soon be officially supported on Mi Box(It is already supported on latest Mi TVs in India).
I can confirm this update is working for me as well. Getting both UltraHD and HDR content. If they added auto frame rate switching, that would complete the set for me.